Wow, we can customize the Toolbar with Tools, that's incredible! I'm requesting a second row of icons

Glad you like it, thank you for the nice feedback!

I've added support for a second Custom Toolbar with Mp3tag v3.34-beta.8. You can configure it via View → Toolbars → Customize custom toolbar....

You can use keyboard shortcuts CtrlE (Show) and CtrlD (Hide) for that.