Can't adda a cover to flac-file on my NAS-server

This is not a bug. This is the expected behaviour - especially for big flac files.

If you add a Cover JPG to a *.flac file it has to be written completely new (in most cases).
This can take a pretty long time and depends highly on your current local network speed and the speed of your NAS hard drives. This seems like "the system hangs".

As you already have found out:
Just copy your *.flac files locally, add the covers and then copy them back to your NAS.

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