Multiple id3s in a wavfile

Yes. You can set the id3 tag type in
Options -> Tags -> Mpeg
Options -> Tags -> Ape, Mpc...

If you ask if it possible to add or edit mulitple ID3 tag type at the same time:
For WAV you can only do that for ID3v1 and ID3v2, but you have to set the subversion v2.3 or v2.4 separately.
Source:
image

I'm just curious:
Why would you like to have both ID3v2.3 AND ID3v2.4 tag types in the same wavfile?